C and Si both have same lattice structure; having 4 bonding electrons in each. However, C is insulator whereas Si is intrinsic semiconductor. This is because
- In case of C the valence band is not completely filled at absolute zero temperature.
- In case of C the conduction band is partly filled even at absolute zero temperature.
- The four bonding electrons in the case of C lie in the second orbit, whereas in the case of Si they lie in the third.
- The four bonding electrons in the case of C lie in the third orbit, whereas for Si they lie in the fourth orbit.
Answer
(3) The four bonding electrons in the case of C lie in the second orbit, whereas in the case of Si they lie in the third.
Solution
The valence electrons of C (2s² 2p²) lie in the second orbit, while those of Si (3s² 3p²) lie in the third orbit.
Electrons in the second orbit are held much more tightly, so the energy gap of C (diamond) is large (Eg 5.4 eV) insulator.
For Si the valence electrons are in the third orbit, less tightly bound, and Eg 1.1 eV semiconductor.
As per NCERT, C (diamond), Si and Ge have the same lattice structure, and their difference in behaviour arises because the four bonding electrons lie in the second, third and fourth orbit respectively.
Answer: (3)