PYQSide ExamsMy practice

Coordination Compounds · Question 28

NEET 2018MatchingEasy📈 Topic in 38% papers+4−1
1

Match the metal ions given in Column I with the spin magnetic moments of the ions given in Column II and assign the correct code :

  1. (a)-(iv), (b)-(v), (c)-(ii), (d)-(i)
  2. (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
  3. (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
  4. (a)-(iii), (b)-(v), (c)-(i), (d)-(ii)

Answer

(1) (a)-(iv), (b)-(v), (c)-(ii), (d)-(i)

Solution

Spin-only magnetic moment: = n(n+2) B.M. (n = number of unpaired electrons).

(a) Co3+: 3d6 ⇒ n = 4 ⇒ = 24 B.M. ⇒ (iv)

(b) Cr3+: 3d3 ⇒ n = 3 ⇒ = 15 B.M. ⇒ (v)

(c) Fe3+: 3d5 ⇒ n = 5 ⇒ = 35 B.M. ⇒ (ii)

(d) Ni2+: 3d8 ⇒ n = 2 ⇒ = 8 B.M. ⇒ (i)

(a)-(iv), (b)-(v), (c)-(ii), (d)-(i)

Answer: (1)

NEET 2018

Keep practising — Coordination Compounds

2

The type of isomerism shown by the complex [CoCl2(en)2] is

  1. geometrical isomerism
  2. coordination isomerism
  3. ionization isomerism
  4. linkage isomerism
NEET 2018
3

The geometry and magnetic behaviour of the complex [Ni(CO)4] are

  1. square planar geometry and diamagnetic
  2. tetrahedral geometry and diamagnetic
  3. square planar geometry and paramagnetic
  4. tetrahedral geometry and paramagnetic
NEET 2018
4

Iron carbonyl, Fe(CO)5 is

  1. tetranuclear
  2. mononuclear
  3. trinuclear
  4. dinuclear
NEET 2018
5

An example of a sigma bonded organometallic compound is

  1. Grignard's reagent
  2. ferrocene
  3. cobaltocene
  4. ruthenocene.
NEET 2017
6

The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes : CoCl3 6NH3, CoCl3 5NH3, CoCl3 4NH3 respectively is

  1. 3AgCl, 1AgCl, 2AgCl
  2. 3AgCl, 2AgCl, 1AgCl
  3. 2AgCl, 3AgCl, 2AgCl
  4. 1AgCl, 3AgCl, 2AgCl
NEET 2017
7

Correct increasing order for the wavelengths of absorption in the visible region for the complexes of Co3+ is

  1. [Co(H2O)6]3+, [Co(en)3]3+, [Co(NH3)6]3+
  2. [Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+
  3. [Co(NH3)6]3+, [Co(en)3]3+, [Co(H2O)6]3+
  4. [Co(en)3]3+, [Co(NH3)6]3+, [Co(H2O)6]3+
NEET 2017
8

Pick out the correct statement with respect to [Mn(CN)6]3-.

  1. It is sp3d2 hybridised and tetrahedral.
  2. It is d2sp3 hybridised and octahedral.
  3. It is dsp2 hybridised and square planar.
  4. It is sp3d2 hybridised and octahedral.
NEET 2017
9

Which of the following has longest C-O bond length? (Free C-O bond length in CO is 1.128 Å.)

  1. [Fe(CO)4]2-
  2. [Mn(CO)6]+
  3. Ni(CO)4
  4. [Co(CO)4]-
NEET 2016 (Phase 1)
10

The correct increasing order of trans-effect of the following species is

  1. NH3 > CN- > Br- > C6H5-
  2. CN- > C6H5- > Br- > NH3
  3. Br- > CN- > NH3 > C6H5-
  4. CN- > Br- > C6H5- > NH3
NEET 2016 (Phase 2)
11

Jahn-Teller effect is not observed in high spin complexes of

  1. d7
  2. d8
  3. d4
  4. d9
NEET 2016 (Phase 2)

All Coordination Compounds PYQs →

PDFDownload Coordination Compounds PYQs as PDF Free, with answer key and a QR code to every solution — print it or study offline⬇
All NEET Chemistry chapters
Physical ChemistrySome Basic Concepts of ChemistryStructure of AtomStates of MatterThermodynamicsEquilibriumRedox ReactionsSolid StateSolutionsElectrochemistryChemical KineticsSurface Chemistry
Inorganic ChemistryClassification of Elements and Periodicity in PropertiesChemical Bonding and Molecular StructureHydrogens-Block Elementsp-Block Elements (Group 13 & 14)Environmental ChemistryGeneral Principles of Isolation of Elementsp-Block Elements (Group 15–18)d- and f-Block ElementsCoordination Compounds
Organic ChemistryOrganic Chemistry – Some Basic Principles and TechniquesIsomerismHydrocarbonsHaloalkanes and HaloarenesAlcohols, Phenols and EthersAldehydes, Ketones and Carboxylic AcidsAminesBiomoleculesPolymersChemistry in Everyday LifePrinciples Related to Practical Chemistry