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Chemical Bonding and Molecular Structure

JEE Main 2024 (Online) 1st February Evening ShiftMCQEasy📈 Topic in 29% papers+4−1
Ques. 1JEE Main 2024, 1 February (Evening Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true

Answer

(4) Statement I is false but Statement II is true

Solution

[figure]

Statement I: π bonding MO = in-phase sideways overlap of p orbitals ⇒ electron density is HIGHER above and below the inter-nuclear axis ⇒ false

Statement II: π* MO = out-of-phase overlap ⇒ a nodal plane between the two nuclei ⇒ true

∵ in-phase lobes merge (bonding), opposite-phase lobes cancel between the nuclei (antibonding).

Answer: (4)

Keep practising — Chemical Bonding and Molecular Structure

Ques. 2JEE Main 2024, 1 February (Evening Shift)

Select the compound from the following that will show intramolecular hydrogen bonding.

  1. [figure]
  2. H2O
  3. C2H5OH
  4. NH3
Ques. 3JEE Main 2024, 31 January (Morning Shift)

The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals Choose the most appropriate from the options given below:

  1. B, C, D only
  2. A, B, C only
  3. B and D only
  4. A and C only
Ques. 4JEE Main 2024, 31 January (Morning Shift)

The number of species from the following in which the central atom uses sp3 hybrid orbitals in its bonding is . NH3, SO2, SiO2, BeCl2, CO2, H2O, CH4, BF3

Ques. 5JEE Main 2024, 31 January (Evening Shift)

Which of the following is least ionic?

  1. CoCl2
  2. KCl
  3. BaCl2
  4. AgCl
Ques. 6JEE Main 2024, 31 January (Evening Shift)

A diatomic molecule has a dipole moment of 1.2 D. If the bond distance is 1 Å, then fractional charge on each atom is 10-1 esu. (Given 1 D = 10-18 esucm)

Ques. 7JEE Main 2024, 30 January (Morning Shift)

Match List I with List II. Choose the correct answer from the options given below :

  1. A-I, B-II, C-IV, D-III
  2. A-IV, B-III, C-I, D-II
  3. A-III, B-IV, C-I, D-II
  4. A-II, B-I, C-III, D-IV
Ques. 8JEE Main 2024, 30 January (Morning Shift)

The total number of molecular orbitals formed from 2s and 2p atomic orbitals of a diatomic molecule is .

Ques. 9JEE Main 2024, 30 January (Evening Shift)

Given below are two statements: In the light of the above statements, choose the most appropriate from the options given below:

  1. Statement I is true but Statement II is false.
  2. Both Statement I and Statement II are true.
  3. Both Statement I and Statement II are false.
  4. Statement I is false but Statement II is true.
Ques. 10JEE Main 2024, 30 January (Evening Shift)

The molecule / ion with square pyramidal shape is

  1. PCl5
  2. [Ni(CN)4]2-
  3. PF5
  4. BrF5
Ques. 11JEE Main 2024, 29 January (Morning Shift)

The number of species from the following which are paramagnetic and with bond order equal to one is . H2, He2+, O2+, N22-, O22-, F2, Ne2+, B2

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