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Some Basic Concepts of Chemistry · Question 26

JEE Main 2025 (Online) 3rd April Evening ShiftMCQMedium📈 Topic in 19% papers+4−1
1

10 mL of 2 M NaOH solution is added to 20 mL of 1 M HCl solution kept in a beaker. Now, 10 mL of this mixture is poured into a volumetric flask of 100 mL containing 2 moles of HCl and made the volume up to the mark with distilled water. The solution in this flask is :

  1. 0.2 M NaCl solution
  2. 20 M HCl solution
  3. Neutral solution
  4. 10 M HCl solution

Answer

(2) 20 M HCl solution

Solution

Moles of NaOH = 2 101000 = 0.02 mol

Moles of HCl = 1 201000 = 0.02 mol

NaOH + HCl NaCl + H2O

Complete neutralisation; the 30 mL mixture contains only 0.02 mol NaCl (neutral).

10 mL of this mixture adds only 0.023 = 6.7 10-3 mol NaCl and no acid or base.

In the flask: moles of HCl = 2 mol, volume = 100 mL = 0.1 L

Molarity of HCl = 20.1 = 20 M

The flask contains 20 M HCl solution.

Answer: (2)

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2

X g of nitrobenzene on nitration gave 4.2 g of m-dinitrobenzene. X = g. (nearest integer) [Given : molar mass (in g mol-1) C : 12, H : 1, O : 16, N : 14]

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CaCO3(s)+2HCl(aq) CaCl2(aq)+CO2(g)+H2O(l) Consider the above reaction, what mass of CaCl2 will be formed if 250 mL of 0.76 M HCl reacts with 1000 g of CaCO3 ? (Given : Molar mass of Ca, C, O, H and Cl are 40, 12, 16, 1 and 35.5 g mol-1, respectively)

  1. 3.908 g
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  3. 10.545 g
  4. 5.272 g
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4

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  1. 60
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5

0.1 mol of the following given antiviral compound (P) will weigh 10-1 g (nearest integer). [figure] (Given : molar mass in g mol-1 H : 1, C : 12, N : 14, O : 16, F : 19, I : 127)

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'x' g of NaCl is added to water in a beaker with a lid. The temperature of the system is raised from 1 C to 25 C. Which out of the following plots, is best suited for the change in the molarity (M) of the solution with respect to temperature? [Consider the solubility of NaCl remains unchanged over the temperature range]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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  3. (C), (D) and (E) Only
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Concentrated nitric acid is labelled as 75% by mass. The volume in mL of the solution which contains 30 g of nitric acid is . Given : Density of nitric acid solution is 1.25 g/mL.

  1. 32
  2. 40
  3. 55
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