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Solutions · Question 10

RE-NEET (UG) 2024MCQMedium📈 Topic in 38% papers+4−1
1

Arrange the following compounds in increasing order of their solubilities in chloroform: NaCl, CH3OH, cyclohexane, CH3CN

  1. NaCl < CH3CN < CH3OH < Cyclohexane
  2. CH3OH < CH3CN < NaCl < Cyclohexane
  3. NaCl < CH3OH < CH3CN < Cyclohexane
  4. Cyclohexane < CH3CN < CH3OH < NaCl

Answer

(1) NaCl < CH3CN < CH3OH < Cyclohexane

Solution

Chloroform is a solvent of low polarity, so "like dissolves like": the less polar the solute, the more soluble it is.

NaCl is ionic → least soluble.

CH3CN is highly polar ( 3.9 D); CH3OH is less polar ( 1.7 D) → CH3OH is more soluble than CH3CN.

Cyclohexane is non-polar → most soluble.

Order: NaCl < CH3CN < CH3OH < cyclohexane

Answer: (1)

RE-NEET (UG) 2024

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2

Mass of glucose ( C6H12O6) required to be dissolved to prepare one litre of its solution which is isotonic with 15 g L-1 solution of urea (NH2CONH2) is (Given: Molar mass in g mol-1 C : 12, H : 1, O : 16, N : 14)

  1. 55 g
  2. 15 g
  3. 30 g
  4. 45 g
RE-NEET (UG) 2024
3

KH value for some gases at the same temperature 'T' are given : [figure] where KH is Henry's Law constant in water. The order of their solubility in water is :

  1. HCHO < CH4 < CO2 < Ar
  2. Ar < CO2 < CH4 < HCHO
  3. Ar < CH4 < CO2 < HCHO
  4. HCHO < CO2 < CH4 < Ar
NEET (UG) 2022 (Phase 2)
4

The following solutions were prepared by dissolving 10 g of glucose ( C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose ( C12H22O11) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is :

  1. P3 > P1 > P2
  2. P2 > P1 > P3
  3. P1 > P2 > P3
  4. P2 > P3 > P1
NEET (UG) 2021
5

The correct option for the value of vapour pressure of a solution at 45 C with benzene to octane in molar ratio 3 : 2 is : [At 45 C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume ideal solution]

  1. 350 mm of Hg
  2. 160 mm of Hg
  3. 168 mm of Hg
  4. 336 mm of Hg
NEET (UG) 2021
6

The freezing point depression constant (Kf) of benzene is 5.12 K kg mol-1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is rounded off upto two decimal places :

  1. 0.80 K
  2. 0.40 K
  3. 0.60 K
  4. 0.20 K
NEET (UG) 2020
7

The mixture which shows positive deviation from Raoult's law is :

  1. Benzene + Toluene
  2. Acetone + Chloroform
  3. Chloroethane + Bromoethane
  4. Ethanol + Acetone
NEET (UG) 2020
8

For an ideal solution, the correct option is :

  1. mix H = 0 at constant T and P
  2. mix G = 0 at constant T and P
  3. mix S = 0 at constant T and P
  4. mix V 0 at constant T and P
NEET (UG) 2019
9

The mixture that forms maximum boiling azeotrope is :

  1. Ethanol + Water
  2. Acetone + Carbon disulphide
  3. Heptane + Octane
  4. Water + Nitric acid
NEET (UG) 2019
10

If molality of the dilute solution is doubled, the value of molal depression constant (Kf) will be

  1. halved
  2. tripled
  3. unchanged
  4. doubled.
NEET 2017
11

Which of the following is dependent on temperature?

  1. Molarity
  2. Mole fraction
  3. Weight percentage
  4. Molality
NEET 2017

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