Coordination Compounds · Question 49

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

1. Both Statement I and Statement II are incorrect
2. Statement I is correct but Statement II is incorrect
3. Statement I is incorrect but Statement II is correct
4. Both Statement I and Statement II are correct

A transition metal (M) among Mn, Cr, Co and Fe has the highest standard electrode potential (M3+/M2+). It forms a metal complex of the type [M(CN)6]4-. The number of electrons present in the eg orbital of the complex is .

The type of hybridization and the magnetic property of [MnCl6]3- are,

1. sp3d2, paramagnetic with four unpaired electrons.
2. d2sp3, paramagnetic with four unpaired electrons.
3. sp3d2, paramagnetic with two unpaired electrons.
4. d2sp3, paramagnetic with two unpaired electrons.

The d-orbital electronic configuration of the complex among [Co(en)3]3+, [CoF6]3-, [Mn(H2O)6]2+ and [Zn(H2O)6]2+ that has the highest CFSE is:

1. t2g6eg0
2. t2g3eg2
3. t2g4eg2
4. t2g6eg4

The correct increasing order of stability of the complexes based on 0 value is : I. [Mn(CN)6]3- II. [Co(CN)6]4- III. [Fe(CN)6]4- IV. [Fe(CN)6]3-

1. I < II < IV < III
2. IV < III < II < I
3. III < II < IV < I
4. II < III < I < IV

Match List - I with List - II. Choose the correct answer from the options given below :

1. (A)-(III), (B)-(I), (C)-(I), (D)-(IV)
2. (A)-(III), (B)-(II), (C)-(III), (D)-(IV)
3. (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
4. (A)-(IV), (B)-(I), (C)-(II), (D)-(III)

Match List - I with List - II. Choose the correct answer from the options given below:

1. (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
2. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
3. (A)-(I), (B)-(IV), (C)-(III), (D)-(II)
4. (A)-(III), (B)-(II), (C)-(I), (D)-(IV)