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Chemical Bonding and Molecular Structure

JEE Main 2024 (Online) 5th April Evening ShiftMCQEasy📈 Topic in 20% papers+4−1
Ques. 1JEE Main 2024, 5 April (Evening Shift)

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the correct answer from the options given below :

  1. (A) is false but (R) is true
  2. (A) is true but (R) is false
  3. Both (A) and (R) are true but (R) is NOT the correct explanation of (A)
  4. Both (A) and (R) are true and (R) is the correct explanation of (A)

Answer

(4) Both (A) and (R) are true and (R) is the correct explanation of (A)

Solution

[figure]

Both: 3 bp + 1 lp on N ⇒ pyramidal

NH3: N–H bond moments point towards N, along the lone-pair moment ⇒ they add

NF3: N–F bond moments point towards F (most electronegative), against the lone-pair moment ⇒ they partly cancel

∴ (NH3) > (NF3) ⇒ (A) true, (R) true and explains (A)

Answer: (4)

Keep practising — Chemical Bonding and Molecular Structure

Ques. 2JEE Main 2024, 5 April (Evening Shift)

Number of compounds from the following with zero dipole moment is . HF, H2, H2S, CO2, NH3, BF3, CH4, CHCl3, SiF4, H2O, BeF2

Ques. 3JEE Main 2024, 4 April (Morning Shift)

Number of molecules/ions from the following in which the central atom is involved in sp3 hybridization is . NO3-, BCl3, ClO2-, ClO3-

  1. 2
  2. 4
  3. 1
  4. 3
Ques. 4JEE Main 2024, 4 April (Morning Shift)

Which one of the following molecules has maximum dipole moment?

  1. CH4
  2. NF3
  3. NH3
  4. PF5
Ques. 5JEE Main 2024, 4 April (Morning Shift)

Number of molecules/species from the following having one unpaired electron is . O2, O2-1, NO, CN-1, O22-

Ques. 6JEE Main 2024, 4 April (Evening Shift)

The correct statement/s about Hydrogen bonding is/are Choose the correct answer from the options given below:

  1. A, B, C only
  2. A only
  3. A, D, E only
  4. A, B, D only
Ques. 7JEE Main 2024, 4 April (Evening Shift)

The number of species from the following that have pyramidal geometry around the central atom is S2O32-, SO42-, SO32-, S2O72-

  1. 4
  2. 3
  3. 2
  4. 1
Ques. 8JEE Main 2024, 4 April (Evening Shift)

Number of compounds / species from the following with non-zero dipole moment is . BeCl2, BCl3, NF3, XeF4, CCl4, H2O, H2S, HBr, CO2, H2, HCl

Ques. 9JEE Main 2024, 1 February (Morning Shift)

Arrange the bonds in order of increasing ionic character in the molecules. LiF, K2O, N2, SO2 and ClF3 :

  1. N2 < SO2 < ClF3 < K2O < LiF
  2. ClF3 < N2 < SO2 < K2O < LiF
  3. LiF < K2O < ClF3 < SO2 < N2
  4. N2 < ClF3 < SO2 < K2O < LiF
Ques. 10JEE Main 2024, 1 February (Morning Shift)

The number of molecules/ion/s having trigonal bipyramidal shape is . PF5, BrF5, PCl5, [PtCl4]2-, BF3, Fe(CO)5

Ques. 11JEE Main 2024, 1 February (Evening Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true

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