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Chemical Bonding and Molecular Structure

JEE Main 2024 (Online) 4th April Morning ShiftMCQEasy📈 Topic in 20% papers+4−1
Ques. 1JEE Main 2024, 4 April (Morning Shift)

Which one of the following molecules has maximum dipole moment?

  1. CH4
  2. NF3
  3. NH3
  4. PF5

Answer

(3) NH3

Solution

CH4 (tetrahedral) and PF5 (trigonal bipyramidal) are symmetrical ⇒ μ = 0

[figure]

∵ in NH3 the N–H moments and the lone-pair moment point the same way (add); in NF3 the N–F moments oppose it

⇒ μ: NH3 (1.47 D) > NF3 (0.23 D) > CH4 = PF5 (0)

Answer: (3)

Keep practising — Chemical Bonding and Molecular Structure

Ques. 2JEE Main 2024, 4 April (Morning Shift)

Number of molecules/species from the following having one unpaired electron is . O2, O2-1, NO, CN-1, O22-

Ques. 3JEE Main 2024, 4 April (Evening Shift)

The correct statement/s about Hydrogen bonding is/are Choose the correct answer from the options given below:

  1. A, B, C only
  2. A only
  3. A, D, E only
  4. A, B, D only
Ques. 4JEE Main 2024, 4 April (Evening Shift)

The number of species from the following that have pyramidal geometry around the central atom is S2O32-, SO42-, SO32-, S2O72-

  1. 4
  2. 3
  3. 2
  4. 1
Ques. 5JEE Main 2024, 4 April (Evening Shift)

Number of compounds / species from the following with non-zero dipole moment is . BeCl2, BCl3, NF3, XeF4, CCl4, H2O, H2S, HBr, CO2, H2, HCl

Ques. 6JEE Main 2024, 1 February (Morning Shift)

Arrange the bonds in order of increasing ionic character in the molecules. LiF, K2O, N2, SO2 and ClF3 :

  1. N2 < SO2 < ClF3 < K2O < LiF
  2. ClF3 < N2 < SO2 < K2O < LiF
  3. LiF < K2O < ClF3 < SO2 < N2
  4. N2 < ClF3 < SO2 < K2O < LiF
Ques. 7JEE Main 2024, 1 February (Morning Shift)

The number of molecules/ion/s having trigonal bipyramidal shape is . PF5, BrF5, PCl5, [PtCl4]2-, BF3, Fe(CO)5

Ques. 8JEE Main 2024, 1 February (Evening Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
Ques. 9JEE Main 2024, 1 February (Evening Shift)

Select the compound from the following that will show intramolecular hydrogen bonding.

  1. [figure]
  2. H2O
  3. C2H5OH
  4. NH3
Ques. 10JEE Main 2024, 31 January (Morning Shift)

The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals Choose the most appropriate from the options given below:

  1. B, C, D only
  2. A, B, C only
  3. B and D only
  4. A and C only
Ques. 11JEE Main 2024, 31 January (Morning Shift)

The number of species from the following in which the central atom uses sp3 hybrid orbitals in its bonding is . NH3, SO2, SiO2, BeCl2, CO2, H2O, CH4, BF3

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