Thermodynamics · Question 31

Three thermochemical equations are given below (i) C(graphite) + O2(g) CO2(g); r H = x kJ mol-1 (ii) C(graphite) + 12O2(g) CO(g); r H = y kJ mol-1 (iii) CO(g) + 12O2(g) CO2(g); r H = z kJ mol-1 Based on the above equations, find out which of the relationship given below is correct.

1. z = x + y
2. x = y + z
3. y = 2z − x
4. x = y − z

Equal volumes of two monoatomic gases, A and B at same temperature and pressure are mixed. The ratio of specific heats (Cp/Cv) of the mixture will be

1. 0.83
2. 1.50
3. 3.3
4. 1.67

In which of the following reactions, standard reaction entropy change ( S ) is positive and standard Gibb's energy change ( G ) decreases sharply with increasing temperature ?

1. C(graphite)+ 12O2(g) CO(g)
2. CO(g)+ 12O2(g) CO2(g)
3. Mg(s)+ 12O2(g) MgO(s)
4. 12C(graphite)+ 12O2(g) 12CO2(g)

The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 C is

1. 10.52 cal/(mol K)
2. 21.04 cal/(mol K)
3. 5.260 cal/(mol K)
4. 0.526 cal/(mol K)

Standard enthalpy of vaporisation vapH for water at 100 C is 40.66 kJ mol-1. The internal energy of vaporisation of water at 100 C (in kJ mol-1) is

1. +37.56
2. -43.76
3. +43.76
4. +40.66

Consider the following processes : array|l|c| & H (kJ/mol) \ 12A B & +150 \ 3B 2C + D & -125 \ E + A 2D & +350 \ array For B + D E + 2C, H will be

1. 525 kJ/mol
2. -175 kJ/mol
3. -325 kJ/mol
4. 325 kJ/mol

If the enthalpy change for the transition of liquid water to steam is 30 kJ mol-1 at 27 , the entropy change for the process would be

1. 10 J mol-1 K-1
2. 1.0 J mol-1 K-1
3. 0.1 J mol-1 K-1
4. 100 J mol-1 K-1

Enthalpy change for the reaction, 4H(g) 2H2(g) is -869.6 kJ The dissociation energy of H-H bond is

1. -434.8 kJ
2. -869.6 kJ
3. +434.8 kJ
4. +217.4 kJ

Which of the following is correct option for free expansion of an ideal gas under adiabatic condition ?

1. q = 0, T 0, w = 0
2. q 0, T = 0, w = 0
3. q = 0, T = 0, w = 0
4. q = 0, T < 0, w 0

Match List I (Equations) with List II (Type of processes) and select the correct option.

1. A - (i), B - (ii), C - (iii), D - (iv)
2. A - (iii), B - (iv), C - (ii), D - (i)
3. A - (iv), B - (i), C - (ii), D - (iii)
4. A - (ii), B - (i), C - (iv), D - (iii)